To find the MAC address of your Sony PlayStation 2 you will need the
Network Adaptor connected to the PS2 and you will need the disc that
came with the Network Adaptor. Then follow these steps:
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Power up the PlayStation 2 and load the Network Adaptor Startup
Disc.
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Once it has loaded, select "ISP Setup" and press X on your
controller.
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The ISP Setup will begin to load, and you will be presented with
a license agreement. Select Agree and press X to continue.
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For connection type, choose "Local Area Network (LAN)" and press
X to continue.
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Select "Automatic Configuration" and press X to continue.
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At the connection test screen, select "Advanced" and press X to
continue.
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At the "Advanced Broadband Settings" screen, make sure
"Automatic" is selected. While you are at this screen, make note
of the MAC address at the bottom.
Some of the PS2 games also have the ability to list your MAC
address, but the above steps is the preferred way of finding the
MAC.